Preparation of high-temperature superconducting materials (HTSC) |
Experimental parameters:
With an increase of irradiation dose up to 5,6х1016 cm-2 temperature of superconducting transition (Tc) increases on ~ 10%, after which it decreases down to its initial values. The increase of Tc is concerned with a change of defect structure of crystal lattice and it evidences a non-optimal structure of the material. In the ideal case which should take place for single crystals, the irradiation should lead to the depresses HTSC critical parameters. Temperature dependences of resistivity Y0,8Sm0,2Ba2Cu3O7 ceramics at different irradiation doses 60Co: Ф=0; 5,6х1016; 10,9х1016 cm-2. On the insets are: upper part – dose dependence of a temperature of the start of superconducting transition; lower part – that of the end of superconducting transition.
In the range of temperatures before the superconducting transition, the phonon contribution to the heat conduction dominates, and the electron contribution has a very low contribution on the heat conduction, which disappears after the material transition into the superconducting state. The anomaly of phonon contribution, which displays a maximum before the superconducting transition, is explained by a suppression of electron-phonon scattering at a formation of the Bose-condensate. Temperature dependence (Т, К) of the heat conduction λ (W/m.K) of the Y-Sm-Ba-Cu-O system. Marked is its phonon component (curve 1) and electron component (curve 2).
Three peaks of heat capacity are observed on the sample after synthesis (curve 1), one of which (low-temperature one) agrees with the superconducting transition temperature of 98К. After 3- and 5-fold thermocycling in the range 4-400 К (curves 2 and 3) peaks lower and then they disappear. Their disappearance is explained by the presence of unstable superconducting states. Temperature dependence (Т,К) of heat capacity ср (W/kg.K) of the Y-Sm-Ba-Cu-O.
We have carried out a number of investigations on the Tl-Ba-Ca-Cu-O system, which has several high-temperature phases, one of which (Тс=125 К) is the largest of all known HTSCs. Temperature dependences of resistivity of 2212 and 2223 samples of the Tl-Ba-Ca-Cu-O system.
Temperature dependences of thermopower of 2212 and 2223 samples of the Tl-Ba-Ca-Cu-O system.
The difference of signs of thermopower and Hall effect is connected with a smaller mobility of holes being compared with that of electrons, though their concentration is smaller. The relationship of concentrations of carriers of both signs remains constant up to the superconducting transition temperature. Temperature dependence of the Hall coefficient and the Hall concentration of carriers per one Cu atom.
Provided here examples of investigations of HTSC materials show that every measurement method has its own specific characteristics and gives information which could not be obtained by means of other methods. Every one of them complements each other and at complex use they make it possible to obtain complete information on electronic and superconducting properties of HTSC materials.
Shanghai Jiao Tong University in the name of Prof. Xin Yao has provided two HTSC single-crystal samples of YBa2Cu3O6 system, in frames of implementation of the joint research project “Correlation of crystallization mechanisms of REBCO with their electrical-physical characteristics” which was accepted according to the decision No.9c-14 by the Intergovernmental Belarusian-Chinese commission in the field of science and technologies.
Temperature dependence of magnetic moment of YBa2Cu3O6 №1 and №2 with magnetic field induction vector B oriented parallel to the crystallographic axis с.
Averaged characteristic of superconducting transition temperature for the magnetic field induction vector B oriented parallel to the crystallographic axis с.
Temperature dependence of magnetic moment of YBa2Cu3O6 сrystals №1 and №2 with magnetic field induction vector B oriented perpendicular to the crystallographic axis с.
Averaged characteristic of superconducting transition temperature for the magnetic field induction vector B oriented perpendicular to the crystallographic axis с.
The following tendency takes place for two orientations of magnetic field induction vector relative to axis с of the HTSC single crystals:
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