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Investigations of the structural characteristic features of Si/SiO2/Metal (Ni, Cu) systems

Atomic force microscopy (AFM) images of the surface of n-Si/SiO2/Ni sample irradiated by 197Au26+ ions with energy 350 MeV and fluence 5×108 cm-2:  (а) – phase-contrast image;  (b) – distribution bar chart of nickel ougrowth heights within the scanned region.

SEM images of n-Si/SiO2/Ni sample, irradiated by 131Xe17+ ions with energy 350 MeV and fluence 5×108 cm-2: (c) top view; (d) cross-sectional view.

 

 

AFM images of n-Si/SiO2/Cu sample, irradiated by 197Au26+ ions with energy 350 MeV and fluence  5×108 cm-2: (а) phase-contrast image;  (b) distribution bar chart of copper ougrowth heights within the scanned region.

(c) SEM image of the n-Si/SiO2/Cu sample irradiated by 131Xe17+ ions with energy 350 MeV and fluence 5×108 cm-2 after its shearing by the focused ion beam. The image was obtained by the “Cross-section” method.

 

X-ray diffraction pattern of Ni in pores of SiO2 layer. Reflexes of silicon substrate and silicon dioxide are exclude.

 

Reflexes (220), (200) and (111) which are characteristic for polycrystalline metallic nickel. Ni crystallites are deposited in the form of nanoclusters with dimensions 30-50 nm which are stochasticlly oriented in the pore. A formation of FCC Ni phase with a characteristic unit cell parameter a = 0.352 nm takes place during the electrodeposition.

 

 

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